کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6583643 | 456359 | 2016 | 36 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Supercritical water gasification of phenol using a Ru/CeO2 catalyst
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Supercritical water gasification of phenol using a Ru/CeO2 catalyst Supercritical water gasification of phenol using a Ru/CeO2 catalyst](/preview/png/6583643.png)
چکیده انگلیسی
Phenols are typical aromatic pollutants and major byproducts of non-catalytic gasification and liquefaction processes. In this work, Ru/CeO2 was prepared and used to catalyze phenol gasification in supercritical water. The catalyst improves carbon efficiency by about 90% at the conditions employed: 0.5 g Ru/CeO2/g phenol catalyst loading at 550 °C with a water density of 0.0979 g/cm3 and a 5 wt% loading of phenol relative to water. This represents a more than 10-fold enhancement of carbon efficiency compared to the noncatalytic case, with CH4 as the major gaseous product. GC-MS results show suppressed formation of dimers, such as dibenzofuran and polycyclic aromatic hydrocarbons (PAHs), which may be caused by the hydrogenation activity of Ru/CeO2. Kinetic modeling of the gasification process gives an activation energy of 84.24 ± 22 kJ/mol and an frequency factor (ln A) of 12.5 ± 2.9 for gaseous product formation, compared to 60 ± 17 kJ/mol and 7.53 ± 2.7 for char formation. Ru/CeO2 is stable in supercritical water at temperatures up to 550 °C, suggesting that a Ru/CeO2 supercritical water gasification system may be a promising method for treating phenols.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 283, 1 January 2016, Pages 358-365
Journal: Chemical Engineering Journal - Volume 283, 1 January 2016, Pages 358-365
نویسندگان
Qingqing Guan, Xiaodian Huang, Jing Liu, Junjie Gu, Rongrong Miao, Qiuling Chen, Ping Ning,