کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6587180 | 456413 | 2013 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Modeling of lead (II) biosorption by residue of allspice in a fixed-bed column
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Residue of allspice (Pimenta dioica L. Merrill) obtained as a by-product from the essential oil supercritical extraction process, has been evaluated as a biosorbent for removing lead (II) from aqueous solutions in batch studies, but not in a practical system like a fixed bed column [12], [13]. In this paper, the effects of flow rate (20 and 40Â mL/min), bed depth (8 and 15Â cm) and influent lead concentration (15 and 25Â mg/L) on the adsorption capacity of the residue of allspice in a fixed-bed column were investigated. The highest adsorption capacity (99.2%) on a 15Â mg/L Pb(II) solution was achieved within a flow rate of 20Â mL/min and a bed depth of 15Â cm. The experimental data obtained from the adsorption process was successfully correlated with the Thomas, Adams-Bohart, Yoon-Nelson, Bed Depth Service Time (BDST), and Dose Response models. A rigorous model based on the differential balance mass transfer was also used to describe the adsorption process in the column. The results of the parameters zone mass transfer, diffusion and mass transfer coefficients obtained with modeling the continuous process could be applied to scale up the process to an actual industrial column.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 228, 15 July 2013, Pages 21-27
Journal: Chemical Engineering Journal - Volume 228, 15 July 2013, Pages 21-27
نویسندگان
J. Cruz-Olivares, C. Pérez-Alonso, C. Barrera-DÃaz, Fernando Ureña-Nuñez, M.C. Chaparro-Mercado, Bryan Bilyeu,