کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6587794 | 456413 | 2013 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Nitrobenzene degradation in Fenton-like systems using Cu(II) as catalyst. Comparison between Cu(II)- and Fe(III)-based systems
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Nitrobenzene (NBE) degradation in Fenton-like systems using copper(II) as catalyst was investigated and compared with the trends observed in iron(III)-based systems. UV-vis spectroscopy, HPLC and TOC measurements were used to characterize the evolution of the reaction mixtures. Kinetic profiles were analyzed under a wide range of experimental conditions in order to assess the effects of the reaction temperature, initial concentrations and working pH. For both Cu(II)-based and Fe(III)-based systems, treatment times decreased with increasing oxidant and catalyst concentrations, but augmented with increasing NBE concentration. However, significant differences were observed for Cu(II)-based systems: higher activation energy above room temperature, broader pH range of activity with an optimal pH of about 6.2, absence of 1,3-dinitrobenzene among the reaction products and important reductions in the TOC levels even in the absence of irradiation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 228, 15 July 2013, Pages 1148-1157
Journal: Chemical Engineering Journal - Volume 228, 15 July 2013, Pages 1148-1157
نویسندگان
Daniela A. Nichela, Andrea M. Berkovic, Mariana R. Costante, MarÃa P. Juliarena, Fernando S. GarcÃa Einschlag,