کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6604997 | 1424097 | 2018 | 36 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Solid oxide fuel cells with proton-conducting La0.99Ca0.01NbO4 electrolyte
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Several proton conductive ceramic oxides are evaluated for potential application in ceramic-NiO composite anodes for proton-conducting La0.99Ca0.01NbO4 (LNO) electrolyte-based fuel cells. Chemical compatibility tests show that most of the existing proton-conducting oxides are unfavorable for application in LNO electrolyte-based fuel cells because of undesirable reactions at high temperatures. Further considering the chemical compatibility with NiO and the ability to promote the densification of the deposited LNO electrolyte, LNO-NiO composite anode proves to be the only suitable anode candidate. With humidified hydrogen (â¼3%H2O) as the fuel and static air as the oxidant, fuel cells based on LNO electrolyte film deposited on LNO-NiO anodes show a peak power density of 24 mW cmâ2 at 750 °C, this value being one of the largest ever reported for LNO-based cells. Further investigation reveals that the polarization resistance of the cell is the major contribution to the total cell resistance, limiting the overall cell performance.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 260, 10 January 2018, Pages 748-754
Journal: Electrochimica Acta - Volume 260, 10 January 2018, Pages 748-754
نویسندگان
Lei Bi, Emiliana Fabbri, Enrico Traversa,