کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6605998 | 459522 | 2016 | 25 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Fabrication and electrochemical characterizations of Nd2NiO4+δ-Ce0.8Gd0.2O2âδ composite cathodes for anode-supported intermediate temperature solid oxide fuel cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Nd2NiO4+δ (NNO)-Ce0.8Gd0.2O2âδ (CGO) composites were investigated as cathodes for intermediate temperature solid oxide fuel cells (IT-SOFCs). Planar NiO-YSZ anode-supported cells in size of 50 mm Ã 50 mm were fabricated with YSZ as the electrolyte. The effects of sintering temperature and the relative proportions of NNO and CGO on the cell performance were investigated in combination with chemical reactivity tests of NNO-YSZ and NNO-CGO. NNO-CGO composite cathodes were successfully sintered on YSZ electrolyte at 1000 °C. By using La0.6Sr0.4CoO3âδ (LSC) as current collector, the cell with 70NNO-30CGO composite cathode sintered at 1000 °C exhibited the highest power density of 620 mW cmâ2 (at 0.7 V) and the lowest polarization resistance of 0.302 Ω cm2 at 800 °C. Short-term durability studies revealed that the degradation of cell performance was attributed to the crack formation on the LSC current collector layer and the delamination between NNO-CGO cathode layer and LSC current collector layer.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 212, 10 September 2016, Pages 303-312
Journal: Electrochimica Acta - Volume 212, 10 September 2016, Pages 303-312
نویسندگان
Silin Li, Hengyong Tu, Lijun Yu, Muhammad Tuoqeer Anwar,