کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6606196 | 459523 | 2016 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical behavior of Sn-Fe alloy film negative electrodes for a sodium secondary battery using inorganic ionic liquid Na[FSA]-K[FSA]
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Sn-Fe alloy thin films were prepared by electroplating of tin on iron substrates and annealing them at 533Â K for 0 to 25Â h. The charge-discharge behavior of the films as negative electrodes for sodium secondary batteries was evaluated using a Na[FSA]-K[FSA] (FSAÂ =Â bis(fluorosulfonyl)amide) ionic liquid at 363Â K. Although the Sn-Fe film without annealing (pure Sn film) showed a relatively high discharge capacity of 730Â mAh (g-Sn)â1 in the first cycle, its capacity rapidly decreased to 30Â mAh (g-Sn)â1 within 10 cycles. In contrast, Sn-Fe films annealed for 2 or 4Â h retained higher discharge capacities of 191 or 82Â mAh (g-Sn)â1 after 100 cycles, respectively, due to the formation of an FeSn2 alloy. Additionally, an FeSn2 film was prepared by removing the SnO layer of the Sn-Fe alloy film that was annealed for 25Â h, and its charge-discharge behavior was investigated.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 211, 1 September 2016, Pages 234-244
Journal: Electrochimica Acta - Volume 211, 1 September 2016, Pages 234-244
نویسندگان
Takayuki Yamamoto, Toshiyuki Nohira, Rika Hagiwara, Atsushi Fukunaga, Shoichiro Sakai, Koji Nitta,