کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6606899 459524 2016 27 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Influence of the binder and preparation process on the positive electrode electrochemical response and Li/S system performances
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Influence of the binder and preparation process on the positive electrode electrochemical response and Li/S system performances
چکیده انگلیسی
In this study, the effect of the binder (PVdF and CMC/NBR) and the preparation process of sulfur electrode ink/slurry on electrochemical performance and cycling behaviour of Li/S cells was investigated. Well-dispersed and homogeneous slurries obtained using high-energy mechanical dispersion (Dispermat®) permit to decrease the impedance response of the electrodes and thus to improve the cycling performances at high C-rates. The main effect of CMC/NBR binder was mostly related to electrode adhesion properties, resulting in better cycle life. A detailed analysis of EIS data gives us an insight into electrode impedance response and their variation depending on the electrode fabrication process and nature/type of a binder.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 210, 20 August 2016, Pages 492-501
نویسندگان
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