کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6607083 | 459524 | 2016 | 20 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Graphite fluoride as a cathode material for primary magnesium batteries with high energy density
ترجمه فارسی عنوان
فلوراید گرافیت به عنوان ماده کاتد برای باتری های منیزیم اولیه با تراکم انرژی بالا
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
Graphite fluorides have become promising electrode materials for lithium batteries while their applications in magnesium batteries are rarely reported. Here we demonstrate for the first time CF0.8 as a cathode material for magnesium batteries with a high discharge capacity of more than 800 mAh gâ1. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and the charge/discharge measurements are used to characterize its structure and electrochemical performance. SEM indicates that CF0.8 sample is a layered structure with the thickness of approximately 300â¼400 nm. The CF0.8 cathode exhibits a high discharge capacity of 813.4 mAh gâ1 after discharging to 0.5 V at 20 mA gâ1 in 0.4 M (PhMgCl)2-AlCl3/THF electrolyte (named as APC/THF). Discharge product MgF2 is confirmed by EDX and XPS measurements. Addition of LiCl to APC/THF solution can not only enhance the gravimetric energy densities but also greatly improve the rate performance. The possible function mechanism is proposed and discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 210, 20 August 2016, Pages 704-711
Journal: Electrochimica Acta - Volume 210, 20 August 2016, Pages 704-711
نویسندگان
Xiaowei Miao, Jun Yang, Wanjing Pan, Hancheng Yuan, Yanna Nuli, Shin-ichi Hirano,