کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6607914 | 459536 | 2016 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical analysis of the triarylimidazole-type organic redox catalysts: Chemical stability and homogeneous electron transfer kinetics for the oxidation of 4-methoxybenzyl alcohol
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Electrochemical analysis of the triarylimidazole-type organic redox catalysts: Chemical stability and homogeneous electron transfer kinetics for the oxidation of 4-methoxybenzyl alcohol Electrochemical analysis of the triarylimidazole-type organic redox catalysts: Chemical stability and homogeneous electron transfer kinetics for the oxidation of 4-methoxybenzyl alcohol](/preview/png/6607914.png)
چکیده انگلیسی
Triarylimidazoles have emerged as novel and useful organic redox catalysts as a result of their straightforward synthesis and tunable oxidation potential. Herein we describe an investigation of the effects of supporting electrolyte and solvent on the chemical reversibility of the triarylimidazole redox couple. Next, the homogeneous electron transfer rate for three triarylimidazole mediators toward the oxidation of 4-methoxybenzyl alcohol was estimated using cyclic voltammetry. The results indicate that the concentration and composition of the conducting salts, especially of the anion, affect the electrochemical performance of the triarylimidazole. Kinetic studies reveal that the smaller the peak potential difference between a mediator and the substrate, the larger the catalytic current and the pseudo first-order homogeneous rate constant.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 199, 1 May 2016, Pages 357-365
Journal: Electrochimica Acta - Volume 199, 1 May 2016, Pages 357-365
نویسندگان
Kui-Yong Zhang, Nan-ning Lu, Seung Joon Yoo, Li-Ming Hu, R.Daniel Little, Cheng-Chu Zeng,