کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6608637 | 459541 | 2016 | 43 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
FexSnyMn1-x-yO2 deposited on MCM-41 as electrode for electrochemical supercapacitor
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
To enhance the specific capacitance, cycling stability and material utilization of manganese dioxide (MnO2) for supercapacitor, MCM-41 (mesoporous silica) was firstly synthesized by hydrothermal method, and then FexSnyMn1-x-yO2 layer deposited on MCM-41 was formed through coprecipitation of MnCO3, SnCl4 and FeCl3, followed by calcination to finally obtain FexSnyMn1-x-yO2@MCM-41 electrodes (FS-MnO2@M electrodes). The structure and composition of FS-MnO2@M electrodes were characterized by using scanning electron microscope (SEM), transmission electron microscope (TEM), nitrogen adsorption (BET), Fourier transform infrared spectroscopy (FT-IR) and X-Ray diffraction spectroscopy (XRD). These results of characterization about FS-MnO2@M particles show FS-MnO2 coatings are successfully deposited on the surface of MCM-41and the average coating thickness of FS-MnO2 is around 50Â nm. The electrochemical performances of FS-MnO2@M electrodes are evaluated and researched by galvanostatic charge-discharge test, cyclic voltammogram (CV) and electrochemical impedance spectroscopy (EIS). The results show that FS-MnO2@M electrodes with porous structure display superior cycling stability at large current work condition in charge-discharge tests and good capacitance performance at high scanning rate in CV tests and FS-MnO2@M electrodes indicate the smaller internal resistance through EIS. And the specific capacitance of FS-MnO2@M reaches 319Â FÂ gâ1 at current density of 2Â AÂ gâ1 with the value remaining 88.37% after 10000 cycles. Therefore, the FS-MnO2@M electrode is desirable to become a novel MnO2 electrode for electrochemical supercapacitor.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 192, 20 February 2016, Pages 328-339
Journal: Electrochimica Acta - Volume 192, 20 February 2016, Pages 328-339
نویسندگان
Yuqing Zhang, Yufeng Zhai,