کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6608984 | 459545 | 2016 | 30 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Layered Li-rich vanadium phosphate Li9V3(P2O7)3(PO4)2: cathode and anode materials for lithium-ion batteries
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this paper, we have prepared the carbon-coated Li9V3(P2O7)3(PO4)2 (LVPP/C) composite via a simple carbon thermal reduction and its lithium inserted-extracted mechanism are systematically investigated. LVPP/C cathode can keep a reversible capacity of 100.6Â mAhgâ1, 98.7% of the initial discharge capacity, after 50 cycles within 2.5Â V-4.6Â V, while an obviously capacity-fading is observed within 2.5Â V-4.8Â V. Meanwhile, the LVPP/C anode delivers a well rate capability and, a reversible capacity of 94.5Â mAhgâ1 (1.0-2.5Â V) can still be retained after 60 cycles, ranging from 0.1C to 2C and finally in 0.1C succession. A good preservation of the LVPP structure is observed during the discharge-charge process by in-situ XRD and an intercalation reaction mechanism is also confirmed for LVPP/C anode here for the first time. At last, a novel symmetrical full battery by using LVPP/C as both cathode and anode simultaneously has been successfully assembled. The investigation shows that this symmetrical cell, with an average voltage of 2.5Â V, can deliver a reversible capacity of 59.8Â mAhgâ1 after 30 cycles at 0.1C.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 191, 10 February 2016, Pages 207-214
Journal: Electrochimica Acta - Volume 191, 10 February 2016, Pages 207-214
نویسندگان
Xinghao Lin, Yanming Zhao, Danlin Yan, Wei Han, Quan Kuang, Mingming Wen,