کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6609028 | 459545 | 2016 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and electrochemical performance of lithium-rich cathode material Li[Li0.2Ni0.15Mn0.55Co0.1-xAlx]O2
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis and electrochemical performance of lithium-rich cathode material Li[Li0.2Ni0.15Mn0.55Co0.1-xAlx]O2 Synthesis and electrochemical performance of lithium-rich cathode material Li[Li0.2Ni0.15Mn0.55Co0.1-xAlx]O2](/preview/png/6609028.png)
چکیده انگلیسی
Lithium-rich layered Li[Li0.2Ni0.15Mn0.55Co0.1-xAlx]O2 (0â¤x<0.1) cathode materials have been synthesized by a sol-gel method followed by high temperature annealing at two stages of 850 °C and 900 °C, respectively. Thermal gravity analysis (TGA), Powder X-ray diffraction (XRD) and Scanning electron microscope (SEM) characterizations prove that the materials have a typical α-NaFeO2 structure, uniform particle size and smooth surface. Electrochemical performance has been investigated by charge-discharge test and the results show that the initial discharge capacity of Li[Li0.2Ni0.15Mn0.55Co0.1-xAlx]O2 (0â¤x<0.1) decreases slightly with the increasing content of Al, but the cycling performance and rate performance have been significantly improved. The optimum amount of Al for the Co is x = 0.05 in consideration of the higher specific capacity and good cyclability. As a consequence, the doped material(x = 0.05) delivers an initial discharge capacity of 231.7mAh·gâ1 at 25 °C with the first columbic efficiency of 75% and 275.8mAh·gâ1 at 55 °C with the first columbic efficiency of 89%, respectively, both at 0.1C within the cut-off voltage range of 2.0 and 4.8 V, which is higher than that of non-substituted material. After 30 cycles, the specific capacity retains 219.1mAh·gâ1 with a capacity retention of 98% for 25 °C, and 248.2mAh·gâ1 with a capacity retention of 96% for 55 °C at 0.5C within the potential range from 2.0 to 4.8 V. These demonstrate that suitable amount of Al3+ substitute for Co3+ in Li[Li0.2Ni0.15Mn0.55Co0.1]O2 facilitates the improvement of the structural stability of materials.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 191, 10 February 2016, Pages 263-269
Journal: Electrochimica Acta - Volume 191, 10 February 2016, Pages 263-269
نویسندگان
Tang Ting, Zhang Hai-Lang,