کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6609350 | 459549 | 2016 | 25 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Graphene oxide-protected three dimensional Se as a binder-free cathode for Li-Se battery
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
Lithium-selenium (Li-Se) battery is attractive because it has the potential to provide high energy density. However, the poor cyclic performance caused mainly by the shuttling of polyselenides and volumetric expansion of selenium limits its practical application. In this paper we report on a facile preparation of selenium on nickel foam by a galvanic replacement method, which can be directly used as a cathode for Li-Se battery without any binders or conductive additives. This material can deliver a capacity of 554 mAh gâ1 (82% of theoretical capacity) and keep a capacity of 137 mAh gâ1 after 100 cycles at a rate of 0.1C. A coating with graphene oxide as protection layer onto the Se surface can further enhance the electrode performance, achieving a capacity of 665 mAh gâ1 (98.5% of theoretical capacity) in the first cycle and remains a capacity of 266 mAh gâ1 after 100 cycles at a rate of 0.1C. The present work demonstrates significant progress in the development of high capacity cathode materials for lithium-selenium battery.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 190, 1 February 2016, Pages 258-263
Journal: Electrochimica Acta - Volume 190, 1 February 2016, Pages 258-263
نویسندگان
Dekang Huang, Shaohui Li, Yanping Luo, Xin Xiao, Lin Gao, Mingkui Wang, Yan Shen,