کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6609657 459546 2015 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effects of anion on the electric double layer of imidazolium-based ionic liquids on graphite electrode by molecular dynamics simulation
ترجمه فارسی عنوان
اثرات آنیون بر لایه ی الکتریکی یونی مایعات بر روی ایزوتوپ گرافیت بر اساس شبیه سازی دینامیک مولکولی
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی
Effects of anion on the electric double layer (EDL) structure and differential capacitance (Cd) of ionic liquid (IL), 1-butyl-3-methyl-imidazolium bis(fluorosulfonyl)imide (BMIM+/FSI−) and 1-butyl-3-methyl-imidazolium trifluoromethanesulfonate (BMIM+/Tf−) on graphite electrode were studied by molecular dynamic simulations. It is found that ILs with FSI− and Tf− anions show substantially different EDL structures and Cd features. The potential-dependent capacitance curve of the BMIM+/FSI− is asymmetric camel-shaped, with the potential of zero charge at the local minimum, while the BMIM+/Tf− shows much weaker Cd dependence on potential between 0 to 1.1 V. Such feature of BMIM+/Tf− indicates formation of Helmholtz-like EDL structure, which consists of a parallel alignment of imidazolium-ring in BMIM+ and the planar graphite electrode. A higher Cd of the both ILs at positive polarization can be attributed to the thinner effective EDL caused by the smaller size of anions compared to the cations. Apart from that, the slightly higher capacitance of BMIM+/Tf− compared to BMIM+/FSI− at positive polarization and the reverse trend at negative polarization is associated with the effectively shortened EDL thickness that resulted from the smaller size of Tf− in contrast to FSI−.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 184, 1 December 2015, Pages 164-170
نویسندگان
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