کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6611096 | 459559 | 2015 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Excellent low temperature performance electrolyte of spiro-(1,1â²)-bipyrrolidinium tetrafluoroborate by tunable mixtures solvents for electric double layer capacitor
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
This paper was addressed on studying the electrolyte for electrochemical double layer capacitors with relatively high ionic conductivity and high electrochemical stability for low temperature application. The data of systematical analysis of the electrochemical characteristics of EDLC have been presented using spiro-(1,1â²)-bipyrrolidinium tetrafluoroborate (SBP-BF4) with 1.5 mol Lâ1 (M) in a variety of solvent compositions including propylene carbonate (PC), ethylene carbonate (EC), dimethyl carbonate (DMC), while the mixture solvents are PC+DMC (1:1 in volume) and PC+DMC+EC (1:1:1 in volume). The physical properties and electrochemical performance of SBP-BF4 in all solvent compositions are investigated. It is found that the binary solvent electrolyte systems exhibited better characteristics in electrochemical performance than single and ternary solvent system in low temperature. The capacitance of the binary solvent electrolyte systems could reach about 117.3 F gâ1 at 20 °C and 92.3 F gâ1 at â50 °C, which were higher than that of single and ternary solvent system. The energy density and power density of EDLCs based on binary solvents systems are can reach 29.6 Wh kgâ1 and 12.5 kW kgâ1, respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 174, 20 August 2015, Pages 215-220
Journal: Electrochimica Acta - Volume 174, 20 August 2015, Pages 215-220
نویسندگان
Zhiqiang Shi, Xuewen Yu, Jing Wang, Hairan Hu, Changcheng Wu,