کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6613510 | 459600 | 2014 | 25 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The catalytic effect of CeO2 for electrochemical oxidation of graphite in molten carbonate
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The catalytic effect of CeO2 for electrochemical oxidation of graphite in molten carbonate The catalytic effect of CeO2 for electrochemical oxidation of graphite in molten carbonate](/preview/png/6613510.png)
چکیده انگلیسی
Direct carbon fuel cell are promising power sources with their performance significantly depending on the anode reaction. In this study, the CeO2 prepared by a Sol-Gel method was investigated as the catalyst for the graphite electrooxidation in the molten alkali carbonate. Ceria and graphite powders with different mass ratios were first homogeneously mixed and then pressed into electrodes for the electrochemical measurements. Results indicated that the performance of graphite electrooxidation was remarkably improved by the addition of CeO2. The current density of the graphite electrooxidation with 50 wt.% ceria reaches 196 mA cmâ2 at -0.4 V vs. Au/CO32-/O2,2CO2 and 750 °C, which is considerably higher than that of pure graphite electrode (117 mA cmâ2). The reaction mechanism relative to the ceria catalytic effect was explained by the indirect electrooxidation pathways via preceding chemical reactions following an electrochemical reaction.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 135, 20 July 2014, Pages 270-275
Journal: Electrochimica Acta - Volume 135, 20 July 2014, Pages 270-275
نویسندگان
Jia Liu, Ke Ye, Kui Cheng, Guiling Wang, Jinling Yin, Dianxue Cao,