کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
66138 48416 2012 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Palladium nano-particles supported on agarose as efficient catalyst and bioorganic ligand for CC bond formation via solventless Mizoroki–Heck reaction and Sonogashira–Hagihara reaction in polyethylene glycol (PEG 400)
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Palladium nano-particles supported on agarose as efficient catalyst and bioorganic ligand for CC bond formation via solventless Mizoroki–Heck reaction and Sonogashira–Hagihara reaction in polyethylene glycol (PEG 400)
چکیده انگلیسی

In this study, abundant naturally occurring agarose has been used as a support and ligand for palladium nanoparticles. In the presence of this catalytic system, Mizoroki–Heck and Sonogashira–Hagihara coupling reactions were performed successfully. The catalyst exhibits high activity in Mizoroki–Heck reaction under phosphane and solvent-free conditions for the reaction of iodo- and bromoarenes with butyl acrylate and styrene. This catalytic system also showed high catalytic activity for Sonogashira–Hagihara coupling reaction of various aryl halides (I, Br, Cl) under copper and ligand-free conditions in polyethylene glycol (PEG 400) as an ecofriendly and non-poisonous media. The catalyst can be separated from the reaction mixture and reused for the similar batches of the reaction. High efficiency of the catalyst along with its recycling ability and the rather low Pd-loading which are demonstrated in both Mizoroki–Heck and Sonogashira–Hagihara reactions are the merits of the presented catalyst system.

The application of palladium nanoparticles supported on agarose in Mizoroki–Heck and Sonogashira–Hagihara reactions.Figure optionsDownload high-quality image (149 K)Download as PowerPoint slideHighlights
► Agarose hydrogel has been used as a support for Pd-nanoparticles.
► Mizoroki–Heck reaction catalyzed by Pd nanoparticles supported agarose hydrogel.
► Pd-nanoparticles on agarose hydrogel catalyzed Sonogashira–Hagihara reaction.
► The catalyst is recyclable.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 357, May 2012, Pages 154–161
نویسندگان
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