کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6614510 | 459623 | 2014 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
X-ray absorption near-edge spectroscopy study on Ge-doped Li7La3Zr2O12: enhanced ionic conductivity and defect chemistry
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: X-ray absorption near-edge spectroscopy study on Ge-doped Li7La3Zr2O12: enhanced ionic conductivity and defect chemistry X-ray absorption near-edge spectroscopy study on Ge-doped Li7La3Zr2O12: enhanced ionic conductivity and defect chemistry](/preview/png/6614510.png)
چکیده انگلیسی
Ge-doped Li7La3Zr2O12 (LLZ) is prepared via the conventional solid-state reaction. Our results showed that doping Ge of less than 1 wt% could stabilize the cubic phase of garnet-type LLZ and also increase its ionic conductivity up to 8.28Â ÃÂ 10â4 S/cm at room temperature. When the content of Ge dopant is higher, GeO2 impurity phase would appear and there coexists cubic and tetragonal mixed structures, lowering the conductivity. By combining X-ray absorption near-edge spectroscopy and full multiple-scattering theory, we find that Ge more likely enters into the Li and La crystallographic sites instead of the Zr site, which provides understanding of the micro-structural modulation by Ge dopants and the subsequent enhancement in the ionic conductivity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 115, 1 January 2014, Pages 581-586
Journal: Electrochimica Acta - Volume 115, 1 January 2014, Pages 581-586
نویسندگان
Mian Huang, Wei Xu, Yang Shen, Yuan-Hua Lin, Ce-Wen Nan,