کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6614726 | 459616 | 2013 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
(Cu6Sn5)1âxCx active/inactive nanocomposite negative electrodes for Na-ion batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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![عکس صفحه اول مقاله: (Cu6Sn5)1âxCx active/inactive nanocomposite negative electrodes for Na-ion batteries (Cu6Sn5)1âxCx active/inactive nanocomposite negative electrodes for Na-ion batteries](/preview/png/6614726.png)
چکیده انگلیسی
The electrochemistry of Sn-Cu-C nanocomposite anode materials in Na-ion cells is described and compared directly to similar compositions from previous work in Li-ion cells. A series of compositions corresponding to (Cu6Sn5)1âxCx (x = 0.15-0.52) was prepared by combinatorial sputtering. This composition range has been shown previously to have good cycling performance in Li-ion cells, having stable capacities near 600 mAh/g for 0.15 < x < 0.45. In contrast, the same composition range was found to have reduced capacity when used in Na-ion cells, having just 350 mAh/g when x = 0.15. Further addition of carbon results in a reduction of reversible capacity to just 135 mAh/g when x = 0.44, however this alloy retains 99% of its 10th cycle capacity of 117 mAh/g after 50 cycles. The potential use and the impact of the addition of carbon to alloy negative electrodes containing Sn for Na-ion batteries are discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 112, 1 December 2013, Pages 133-137
Journal: Electrochimica Acta - Volume 112, 1 December 2013, Pages 133-137
نویسندگان
J.S. Thorne, R.A. Dunlap, M.N. Obrovac,