On the role of noncovalent interactions in electrocatalysis. Two cases of mediated reductive dehalogenation

- Noncovalent forces explain the electrocatalytic effects.
- Transient {MoIOalkoxide}−⋯HCCl3 with exceptionally strong CH⋯O H-bonding.
- Halogen bond and dispersive interactions in HBCD-porphyrin adduct enhance electron transfer.
- Effects of van der Waals interactions on the structure and energetics.