کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6616083 | 459630 | 2013 | 28 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Small-sized Pt particles on mesoporous hollow carbon spheres for highly stable oxygen reduction reaction
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Mesoporous hollow carbon spheres (HCSs) are prepared using glucose as carbon source and solid core mesoporous shell silica spheres (SCMSSs) as templates. Pt particles are then loaded on the HCSs as electrocatalyst and used for oxygen reduction reaction (ORR) in acidic media. Physical measurements display that the HCSs have high surface area (1163Â m2Â gâ1), large pore volume (2.8Â cm3Â gâ1) and mesoporous structure (9.8Â nm in diameter), which are favorable for uniform dispersion and stable loading of small-sized Pt particles, and efficiently improve the mass transfer in catalytic reactions. Cyclic voltammogram measurements show that the mass current density on Pt/HCS electrocatalyst (192.2mAmgPtâ1) is 1.7 times as high as that of commercial Pt/C (TKK) for ORR. Furthermore, the mesopores of HCSs give Pt/HCS more electrocatalytic stability due to stronger physical interaction force.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 109, 30 October 2013, Pages 256-261
Journal: Electrochimica Acta - Volume 109, 30 October 2013, Pages 256-261
نویسندگان
Zaoxue Yan, Jimin Xie, Sekai Zong, Mingmei Zhang, Qian Sun, Min Chen,