کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6617481 | 459633 | 2013 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Zn5(OH)8Cl2·H2O-based quantum dots-sensitized solar cells: A common corrosion product enhances the performance of photoelectrochemical cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Exploiting new and efficient wide-band gap semiconductors is an important way to improve the performance of photoelectrochemical cells (dye-sensitized solar cells (DSSCs) and quantum dots-sensitized solar cells (QDSCs)). In this paper, Zn5(OH)8Cl2·H2O semiconductor that is a common corrosion product for zinc-contained materials in the electrolytes containing Clâ ions is for the first time explored as wide-band gap semiconductor in the photoelectrode of photoelectrochemical cells. The QDSCs based on CdS QDs-sensitized Zn5(OH)8Cl2·H2O nanosheets achieve the promising power conversion efficiencies of 0.62% and 1.11% for Pt and Cu2S counter electrodes, respectively. Furthermore, combining Zn5(OH)8Cl2·H2O and ZnO to form ZnO/Zn5(OH)8Cl2·H2O composite photoelectrode greatly increases the conversion efficiencies of QDSCs to 1.39% and 1.92% for Pt and Cu2S counter electrodes, respectively, which are higher than those based on conventional ZnO (1.11% and 1.53% for Pt and Cu2S counter electrodes, respectively) or TiO2 porous films (1.07% for Pt counter electrode). Therefore, Zn5(OH)8Cl2·H2O has shown much promise as an efficient wide-band gap semiconductor in the photoelectrode of photoelectrochemical cells.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 105, 30 August 2013, Pages 289-298
Journal: Electrochimica Acta - Volume 105, 30 August 2013, Pages 289-298
نویسندگان
Haining Chen, Liqun Zhu, Huicong Liu, Weiping Li,