کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6617580 | 459633 | 2013 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Simultaneous quartz microbalance and mirage effect studies of poly(3-methoxythiophene) electrosynthesis and electrochemical characterisations
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
This work characterises the electropolymerisation of 3-methoxythiophene and presents an electrochemical study of poly(3-methoxythiophene) by cyclic voltammetry using different electrolytes in solvent mixture of water-acetonitrile (3:1, v/v) at 25 °C. Simultaneous measurements of the mirage effect and the quartz microbalance were also performed. This study evaluated the influence of cations on the electrochemical properties of monomers and polymers and allowed us to observe an anomalous behaviour of the synthesised polymer in the presence of potassium ions (K+) when compared with other cations. The reversibility of the polymers was also evaluated with respect to the various electrolytes and was observed the influence of the polymer film thickness (deposited mass) on its electrochemical properties.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 105, 30 August 2013, Pages 347-352
Journal: Electrochimica Acta - Volume 105, 30 August 2013, Pages 347-352
نویسندگان
Marcos Roberto de Abreu Alves, Raphael Nasser Capistrano Reis, Jean Gomes de Oliveira, Hállen Daniel Rezende Calado, Claudio Luis Donnici, Tulio Matencio,