کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6618018 459641 2013 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Oxygen release from high-energy xLi2MnO3·(1 − x)LiMO2 (M = Mn, Ni, Co): Electrochemical, differential electrochemical mass spectrometric, in situ pressure, and in situ temperature characterization
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Oxygen release from high-energy xLi2MnO3·(1 − x)LiMO2 (M = Mn, Ni, Co): Electrochemical, differential electrochemical mass spectrometric, in situ pressure, and in situ temperature characterization
چکیده انگلیسی
As a positive electrode material for Li-ion batteries, xLi2MnO3·(1 − x)LiMO2 (M = Mn, Ni, Co) boasts various advantages compared to LiCoO2, such as higher specific charge (∼250 Ah/kg) and lower cobalt content. However, the oxygen release reaction at ∼4.5 V vs. Li+/Li is not fully understood. xLi2MnO3·(1 − x)LiMO2 has been characterized by a combination of complementary methods, including electrochemical cycling at different temperatures, differential electrochemical mass spectrometry (DEMS), in situ pressure measurement, and in situ temperature measurement. The reaction at ∼4.5 V vs. Li+/Li leads to the exothermic release of oxygen and a significant pressure build-up in the cell. Despite this, the electrochemical performance of the material is very promising. Finally, it is shown that the cells should be operated close to room temperature.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 93, 30 March 2013, Pages 114-119
نویسندگان
, , , ,