کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6633012 | 461089 | 2016 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Characterisation of volatile organic sulphur compounds release during coal pyrolysis in inert, hydrogen and CO2 atmosphere
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
The effects of CO2 atmosphere on the distribution of volatile organic sulphur compounds during coal pyrolysis and the effect of kaolin addition were studied. Sulphur compounds release was determined by atmospheric pressure-temperature programmed reduction “on-line” coupled with MS (AP-TPR/MS) and “off-line” coupled with GC/MS after thermal desorption (AP-TPR-TD-GC/MS). The results show that thiophene and methyl and ethyl substituted analogues were released between 400 and 500 °C, while relatively more complex organic sulphur compounds such as benzothiophene and methyl benzothiophene evolved at higher temperature. In CO2, thiophenes evolved at lower temperature due to its more reactive and oxidative character. With kaolin addition, an increase in most registered volatile organic sulphur compound amounts was noticed both in inert and CO2 gas, due to the catalytic effect of kaolin.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 184, 15 November 2016, Pages 304-313
Journal: Fuel - Volume 184, 15 November 2016, Pages 304-313
نویسندگان
Ying Gu, Jan Yperman, Guy Reggers, Robert Carleer, Jens Vandewijngaarden,