کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6637398 | 461141 | 2014 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
1H NMR spectroscopy and low-field relaxometry for predicting viscosity and API gravity of Brazilian crude oils - A comparative study
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
1H NMR spectra and transversal relaxation time (T2) distributions of 76 Brazilian crude oil samples, ranging from light to extra-heavy, were measured and compared by Hierarchical Clustering Analysis (HCA) and Principal Component Analysis (PCA). Partial Least Squares Regression (PLSR) models were developed to predict crude oil viscosity and density in terms of the American Petroleum Institute (API) gravities derived from their individual NMR responses. Relaxation-based models delivered better predictive performances for both viscosity and API, with a standard error of prediction (SEP) of 0.220 log cP and 1.027 oAPI. In addition, the synergistic effect between the two distinct NMR responses was evaluated for the first time by merging spectra and relaxation data into a single PLSR model. This hybrid spectra-relaxation model delivered superior performance compared to stand-alone models, with an SEP of 0.186 log cP and 0.811 oAPI.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 130, 15 August 2014, Pages 126-134
Journal: Fuel - Volume 130, 15 August 2014, Pages 126-134
نویسندگان
Asif Muhammad, Rodrigo Bagueira de Vasconcellos Azeredo,