کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6638641 | 461164 | 2014 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Determination of API gravity, kinematic viscosity and water content in petroleum by ATR-FTIR spectroscopy and multivariate calibration
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this work, API gravity, kinematic viscosity and water content were determined in petroleum oil using Fourier transform infrared spectroscopy with attenuated total reflectance (FT-IR/ATR). Support vector regression (SVR) was used as the non-linear multivariate calibration procedure and partial least squares regression (PLS) as the linear procedure. In SVR models, the multiplication of the spectra matrix by support vectors resulted in information about the importance of the original variables. The most important variables in PLS models were attained by regression coefficients. For API gravity and kinematic viscosity these variables correspond to vibrations around 2900Â cmâ1, 1450Â cmâ1 and below to 720Â cmâ1 and for water content, between 3200 and 3650Â cmâ1, around 1650Â cm-1 and below to 900Â cmâ1. The SVR model produced a root mean square error of prediction (RMSEP) of 0.25 for API gravity, 22Â mm2Â sâ1 for kinematic viscosity and 0.26%Â v/v for water content. For PLS models, the RMSEP values for API gravity was 0.38Â mm2Â sâ1, for kinematic viscosity was 27Â mm2Â sâ1 and for water content was 0.34%. Using the F-test at 95% of confidence it was concluded that the SVR model produced better results than PLS for API gravity determination. For kinematic viscosity and water content the two methods were equivalent. However, a non-linear behavior in the PLS kinematic viscosity model was observed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 116, 15 January 2014, Pages 123-130
Journal: Fuel - Volume 116, 15 January 2014, Pages 123-130
نویسندگان
Paulo R. Filgueiras, Cristina M.S. Sad, Alexandre R. Loureiro, Maria F.P. Santos, Eustáquio V.R. Castro, Júlio C.M. Dias, Ronei J. Poppi,