کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6639909 | 461153 | 2013 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
In situ preparation of K2CO3 supported Kraft lignin activated carbon as solid base catalyst for biodiesel production
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: In situ preparation of K2CO3 supported Kraft lignin activated carbon as solid base catalyst for biodiesel production In situ preparation of K2CO3 supported Kraft lignin activated carbon as solid base catalyst for biodiesel production](/preview/png/6639909.png)
چکیده انگلیسی
In this study, the catalysts K2CO3 supported Kraft lignin activated carbon (K2CO3/KLC) were prepared in situ by simply mixing K2CO3 with technical Kraft lignin (KL) and subsequently activating at 800 °C for 2 h under N2 flow. The precursor and catalysts were characterized by thermal gravity analysis (TGA), Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) surface area. The catalytic performance of prepared catalysts was evaluated by transesterification of rapeseed oil with methanol. The effects of various parameters on biodiesel yield were investigated. The biodiesel yield of 99.6% was achieved by using the catalyst prepared by 0.6 of K2CO3/KL mass ratio and activation at 800 °C, under the transesterification condition of 65 °C, 2 h, methanol to rapeseed oil molar ratio of 15:1 and 3.0 wt.% catalyst (relative to the weight of rapeseed oil). The solid catalyst can be reused for 4 times and biodiesel yield remained over 82.1% for the fourth time.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 113, November 2013, Pages 435-442
Journal: Fuel - Volume 113, November 2013, Pages 435-442
نویسندگان
Xian-fa Li, Yong Zuo, Ying Zhang, Yao Fu, Qing-xiang Guo,