کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
66548 | 48437 | 2010 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Baeyer–Villiger oxidation of cyclic ketones using Fe containing MCM-48 cubic mesoporous materials Baeyer–Villiger oxidation of cyclic ketones using Fe containing MCM-48 cubic mesoporous materials](/preview/png/66548.png)
Iron containing cubic mesoporous MCM-48 materials were prepared by a modified Stöber synthesis method. These materials were characterized by powder X-ray diffraction (XRD), nitrogen isotherms, diffuse-reflectance UV–Vis spectroscopy, and electron microscopy. These materials exhibited high catalytic activity towards the Baeyer–Villiger oxidation of cyclic ketones using benzaldehyde and molecular oxygen. The Fe-MCM-48 mesoporous materials showed excellent recyclability and the integrity of the cubic phase was preserved after the catalytic activity.
Fe-MCM-48 mesoporous materials were prepared at room temperature and characterized by a variety of techniques. These materials exhibited high catalytic activity towards the Baeyer–Villiger oxidation of cyclic ketones.Figure optionsDownload high-quality image (323 K)Download as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 330, Issues 1–2, 1 September 2010, Pages 66–72