The effect of carbon dioxide partial pressure on the gasification rate and pore development of Highveld coal chars at elevated pressures

Surface analyses were performed on fresh and partially converted chars to quantify the effect of CO2 partial pressure on pore development. It was found that pores development more rapidly with conversion if the CO2 partial pressure is increased. This outcome has fundamental implications for the interpretations of gasification reaction kinetics. The term describing the total amount of active sites in the Langmuir Hinshelwood equation might not be constant at all partial pressures, and the possible impact of that is shown in this work. More work is required to further understand these effects and incorporate them appropriately into high pressure rate equations.