کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6656429 | 1425373 | 2018 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Role of hydrogen donor and non-donor binary solvents in product distribution and hydrogen consumption during direct coal liquefaction
ترجمه فارسی عنوان
نقش اهداکنندگان هیدروژن و حلال های دوتایی غیر اهدا کننده در توزیع محصول و مصرف هیدروژن در حین مایع سازی مستقیم زغال سنگ
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کلمات کلیدی
مایع سازی مستقیم ذغال سنگ، حلالهای دوتایی، مصرف هیدروژن، تبدیل 1-متیل ناتالن،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
Direct liquefaction of Chinese Hami sub-bituminous coal was conducted with binary mixtures of hydrogen donor solvent tetralin (THN) and non-donor 1-methylnaphthalene (1-MN) or naphthalene (Nap.). Effects of solvent composition, temperature, atmosphere, and catalyst FeS2 on product distribution and hydrogen consumption were investigated at solvent/coal mass ratio of 2. The results show that oil yield increases from 47.70% to 59.95% with 1-MN/THN ratio changing from 2:1 to 1:2. Hydrogen donating ability of binary solvents increases with the rising ratio of THN. H2 contributes noticeably positive effect on coal conversion in the case of liquefaction with insufficient hydrogen donor solvent. Oil yield obtained during direct coal liquefaction (DCL) with Nap./THN is 58.32%, which is 10.62% higher than that with 1-MN/THN at same solvent ratio of 2:1. This is owing to demethylation effect of 1-MN under liquefaction condition. 1-MN demethylation is induced by active hydrogen and coal radicals, and could consume noticeable hydrogen during DCL. This indicates that the amount of alkylarenes included in liquefaction mixed solvents should be limited, or sufficient hydrogen donor solvent is required to achieve high coal conversion.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel Processing Technology - Volume 173, May 2018, Pages 75-80
Journal: Fuel Processing Technology - Volume 173, May 2018, Pages 75-80
نویسندگان
Pan Hao, Zong-Qing Bai, Zhi-Tong Zhao, Ze-Feng Ge, Ran-Ran Hou, Jin Bai, Zhen-Xing Guo, Ling-Xue Kong, Wen Li,