کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6659700 | 1426190 | 2018 | 31 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Solubility, acid-base properties and thermodynamics of interaction between three NTA-phosphonate derivatives and the main cationic components (H+, Na+, Mg2+ and Ca2+) of natural fluids
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Solution thermodynamics of three aminophosphonic acids are studied in this work. In particular, the protonation constants [ log(KiH/mol kgâ1)] of N-phosphonomethyliminodiacetic acid (NTAP), N,N-Bis(phosphonomethyl)glycine (NTAP2) and Nitrilotris(methylenephosphonic acid) (NTAP3) and the solubility of NTAP were determined by potentiometric measurements (ISE-[H+] glass electrode) in three different ionic media, namely NaCl(aq), (CH3)4NCl(aq) and (C2H5)4NI(aq) at different ionic strengths (in the range 0â¯<â¯I/mol kgâ1 ⤠1.7) and at Tâ¯=â¯298.15. In NaCl(aq), measurements were performed also at Tâ¯=â¯283.15â¯K and 318.15â¯K. The dependence of the logKiH on ionic strength and temperature was studied by Debye-Hückel type equation and by Specific ion Interaction Theory (SIT). At infinite dilution, the refined values of the first protonation constants are: log(KiH/mol kgâ1)â¯=â¯11.4â¯Â±â¯0.1, 12.4â¯Â±â¯0.1 and 13.3â¯Â±â¯0.1 for NTAP, NTAP2 and NTAP3, respectively and the enthalpy changes relative to the first protonation step are: â15.7â¯Â±â¯0.3, â20.5â¯Â±â¯0.4 and -33.5â¯Â±â¯0.2â¯kJâ¯molâ1 (same order). The basicity trend: NTAP3â¯>â¯NTAP2â¯>â¯NTAP is observed in all the ionic media. The differences in the values of the protonation constants obtained in the three ionic media were also interpreted in terms of formation of weak complex and eleven Na+/L species are obtained using the so called ÎpK method. Solubility investigations performed on NTAP allowed us to determine the Setschenow and the activity coefficients of the neutral species. The values of the total and specific solubility in pure water are: log (S0T/mol kgâ1)â¯=â¯â1.431â¯Â±â¯0.003 and log (S00/mol kgâ1)â¯=â¯â2.293â¯Â±â¯0.006, respectively. The formation constants of the three ligands with Ca2+ and Mg2+ cations were determined at Tâ¯=â¯298.15â¯K in NaCl(aq) at Iâ¯=â¯0.151â¯molâ¯kgâ1, finding the presence of the ML and MHL species. The stability of the Ca2+/L is slightly higher than that of the Mg2+/L ones.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 123, August 2018, Pages 117-127
Journal: The Journal of Chemical Thermodynamics - Volume 123, August 2018, Pages 117-127
نویسندگان
Clemente Bretti, Concetta De Stefano, Gabriele Lando, Silvio Sammartano,