کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6660303 | 1426222 | 2015 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Cation effect on the (PEG 8000Â +Â sodium sulfate) and (PEG 8000Â +Â magnesium sulfate) aqueous two-phase system: Relative hydrophobicity of the equilibrium phases
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The partitioning of four dinitrophenylated (DNP-) amino acids in aqueous two-phase systems of (polyethylene glycol (PEG)-8000 + sodium sulfate) and (polyethylene glycol (PEG)-8000 + magnesium sulfate) in five different tie-lines was experimentally determined at T = 298.15 K. The Gibbs energy of transfer of a methylene group between the two phases was calculated from the measured partition coefficients. This characterizes the relative hydrophobicity of the equilibrium phases. Values of ÎGâ(CH2) were in range from (â0.674 to â1.012) kJ · molâ1. A comparison of both systems was carried out. The results show that the cation type has a strong influence on the amino acids partitioning process. The largest relative hydrophobicity was noted for the ATPS system formed by sodium sulfate. This showed to be a better system for the separation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 91, December 2015, Pages 321-326
Journal: The Journal of Chemical Thermodynamics - Volume 91, December 2015, Pages 321-326
نویسندگان
Kamila Wysoczanska, Sara C. Silvério, José A. Teixeira, Eugénia A. Macedo,