کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6663792 | 463343 | 2008 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Voltammetric and spectroelectrochemical properties of titanylphthalocyanines bearing catecholato and naphthalenediolato moieties
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Detailed electrochemical characterization of catecholato-octakis(2-dimethylaminoethylsulfanyl phthalocyaninato) titanium(IV) and (2,3-naphthalenediolato)-octa-(2-dimethylaminoethylsulfanylphthalocyaninato) titanium(IV) derivatives has been carried out by cyclic voltammetry, differential pulse voltammetry, double potential step coulometry, controlled potential coulometry and spectroelectrochemical measurements. Cyclic and differential pulse voltammograms of the complexes are similar with two metal-based and two ligand-based reduction and two ligand-based oxidation couples. Capping of TiO core of octakis(2-dimethylaminoethylsulfanyl)phthalocyaninato oxotitanium(IV) with catecholato and naphthalenediolato changed the redox mechanism of the complexes. (2,3-naphthalenediolato)-octa-(2-dimethylaminoethylsulfanylphthalocyaninato) titanium(IV) derivative is dimetallised during the negative potential sweeps. Spectroelectrochemical measurements confirm the metal- and ligand-based assignments of the redox couples. Distinctive voltammetric and spectroscopic changes during the titration with soft metal ions, Ag+ and Pd2+, shows the metal sensing and coordinating properties of the complexes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Electroanalytical Chemistry - Volume 616, Issues 1â2, 1 May 2008, Pages 107-116
Journal: Journal of Electroanalytical Chemistry - Volume 616, Issues 1â2, 1 May 2008, Pages 107-116
نویسندگان
Atıf Koca, Yasin ArslanoÄlu, Esin Hamuryudan,