کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6663984 | 1427042 | 2018 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Facile synthesis, characterization and photocatalytic performance of Zn3(PO4)2 platelets toward photodegradation of Rhodamine B dye
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
In this study, we have successfully prepared the zinc phosphate Zn3(PO4)2 through aqueous precipitation using PEG (Polyethylene glycol) as surface active agent. The compound was analyzed by X-Ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-Ray analysis (EDS). The diffraction profiles showed a highly crystallized sample with dimensions of 3â¯Î¼m. Rietveld refinement confirmed the pure monoclinic C2/c zinc phosphate phase. The SEM images showed platelet faceted morphology with different orientations and a crystal growth mechanism has been proposed. The photocatalytic experiments were carried out using Rhodamine B (RhB) as a model pollutant; the UV-visible spectrometry was used to analyze the evolution of dye degradation. The obtained experimental results showed that the Rhodamine B dye degradation efficiency is significantly dependent on different physico-chemical conditions including catalyst loading, pH and dye concentration. Furthermore, the zinc phosphate photocatalyst was found to be fairly photostable during four regeneration cycles. Finally, a photocatalytic mechanism was proposed based on the active species trapping experiments.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Environmental Chemical Engineering - Volume 6, Issue 2, April 2018, Pages 1840-1847
Journal: Journal of Environmental Chemical Engineering - Volume 6, Issue 2, April 2018, Pages 1840-1847
نویسندگان
Y. Naciri, H. Ait Ahsaine, A. Chennah, A. Amedlous, A. Taoufyq, B. Bakiz, M. Ezahri, S. Villain, A. Benlhachemi,