کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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66823 | 48452 | 2010 | 10 صفحه PDF | دانلود رایگان |
Neutral Pd(X)(η3-allyl) (X = Cl, OAc (acetate)) complexes bearing mono-coordinating NHC ligands have been synthesized, characterized and employed to catalyze the aerobic oxidation of unprotected 1,2- and 1,3-diols selectively to hydroxy ketones. A comparison of the catalytic performance of these precursors with a reference system has shown that the precursor with the ligands N,N′-bis(adamantyl)imidazol-2-ylidene and chloride is the most efficient for the chemoselective oxidation of 1,2-diols is concerned. High-pressure 1H NMR (HPNMR) experiments in combination with catalytic batch reactions have provided valuable information on the activation of the precursor as well as on the stability of the catalysts.
Neutral Pd(X)(η3-allyl) (X = Cl, OAc) complexes bearing mono-coordinating NHC ligands have been used to catalyze the aerobic oxidation of unprotected 1,2- and 1,3-diols yielding hydroxy ketones as the only product.Figure optionsDownload high-quality image (106 K)Download as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 322, Issues 1–2, 1 May 2010, Pages 63–72