کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
66876 48455 2010 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Direct synthesis of hydrogen peroxide from hydrogen and oxygen over palladium catalyst supported on SO3H-functionalized mesoporous silica
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Direct synthesis of hydrogen peroxide from hydrogen and oxygen over palladium catalyst supported on SO3H-functionalized mesoporous silica
چکیده انگلیسی

Palladium catalysts supported on SO3H-functionalized mesoporous silicas (denoted as Pd/SO3H-MCM-41, Pd/SO3H-MCM-48, Pd/SO3H-MSU-1, Pd/SO3H-SBA-15, and Pd/SO3H-MCF) were applied to the direct synthesis of hydrogen peroxide from hydrogen and oxygen. For comparison, palladium catalysts supported on mesoporous silicas (denoted as Pd/MCM-41, Pd/MCM-48, Pd/MSU-1, Pd/SBA-15, and Pd/MCF) were also employed for the direct synthesis of hydrogen peroxide. Selectivity for hydrogen peroxide, yield for hydrogen peroxide, and final concentration of hydrogen peroxide over Pd/SO3H-functionalized mesoporous silica catalysts were much higher than those over Pd/mesoporous silica catalysts. Yield for hydrogen peroxide increased with increasing acid density of Pd/SO3H-functionalized mesoporous silica. Pd/SO3H-functionalized mesoporous silicas efficiently served as an alternate acid source and as an active metal catalyst in the direct synthesis of hydrogen peroxide from hydrogen and oxygen.

Palladium catalysts supported on SO3H-functionalized mesoporous silicas (Pd/SO3H-MCM-41, Pd/SO3H-MCM-48, Pd/SO3H-MSU-1, Pd/SO3H-SBA-15, and Pd/SO3H-MCF) were applied to the direct synthesis of hydrogen peroxide from hydrogen and oxygen. Yield for hydrogen peroxide increased with increasing acid density of the catalyst. The catalysts efficiently served as an alternate acid source and as an active metal component in the reaction.Figure optionsDownload high-quality image (91 K)Download as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 319, Issues 1–2, 17 March 2010, Pages 98–107
نویسندگان
, , , , , ,