کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
66929 | 48457 | 2009 | 4 صفحه PDF | دانلود رایگان |
The hydrolysis of methyl bromide with neutral water is performed in the presence and absence of various amines in a batch reactor at different temperatures (50–125 °C). Screening of poly(4-vinylpyridine) as a potential reusable solid amine catalyst showed maximum efficiency. This significant enhancement in efficiency is due to the capture of HBr by solid PVP and remains phase-separated driving the reaction forward. The major advantage of this process is that the polymer can be easily regenerated and reused without loss of activity making it a very effective catalyst for the conversion of methyl halides to methanol and dimethyl ether.
The hydrolysis of methyl bromide with neutral water is performed in the presence and absence of various amines in a batch reactor at different temperatures (50–125 °C). Screening of poly(4-vinylpyridine) as a potential reusable solid amine catalyst showed maximum efficiency. This significant enhancement in efficiency is due to the capture of HBr by solid PVP and remains phase-separated driving the reaction forward. The major advantage of this process is that the polymer can be easily regenerated and reused without loss of activity making it a very effective catalyst for the conversion of methyl halides to methanol and dimethyl ether.Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 310, Issues 1–2, 1 September 2009, Pages 180–183