Role of enthalpy and entropy in moisture sorption behavior of pineapple pulp powder produced by different drying methods

Sorption mechanisms of pineapple powders produced by vibro-fluidized drying (VFD), spray drying (SD), freeze drying (FD) or vacuum drying (VD) were interpreted through enthalpy/entropy variations with respect to equilibrium moisture content (EMC) at 20, 30, 40 and 50 °C and water activity (aw) between 0.059 and 0.907. Powders from SD and VFD were more hygroscopic and integral properties indicated higher stability at changing aw compared to powders from VD and FD. Powders showed an enthalpy driven zone with equal isokinetic temperature (TB1 = 499.0 ± 4.8 K) due to their same composition, and an entropy controlled zone with different isokinetic temperature, TB2 (VD: 116.0 ± 40.6 K; FD: 118.3 ± 24.1 K; SD: 95.8 ± 23.4 K; VFD: 81.8 ± 6.3 K), caused by different microstructures resulting from different drying methods. Powders from SD and VFD presented larger entropic zones that shifted the minimum integral entropy to higher aw, improving storage stability.

► Sorption mechanisms of pineapple powders produced by different drying methods were interpreted through enthalpy/entropy variations.
► Powders from spray and vibro-fluidized drying were more hygroscopic compared to powders from vacuum and freeze drying.
► Integral properties indicated higher stability of the powders from spray and vibro-fluidized drying compared to powders from vacuum and freeze drying.
► Powders showed an enthalpy driven zone with equal isokinetic temperature and an entropy controlled zone with different isokinetic temperature.
► Powders from spray and vibro-fluidized drying presented larger entropic zones that shifted the minimum integral entropy to higher aw.