کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
67658 | 48490 | 2007 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Oxidative kinetic resolution of racemic secondary alcohols catalyzed by recyclable chiral dimeric Mn(III) salen catalysts
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Oxidative kinetic resolution of racemic secondary alcohols catalyzed by recyclable chiral dimeric Mn(III) salen catalysts Oxidative kinetic resolution of racemic secondary alcohols catalyzed by recyclable chiral dimeric Mn(III) salen catalysts](/preview/png/67658.png)
چکیده انگلیسی
The oxidative kinetic resolution of racemic secondary alcohols was efficiently catalyzed by chiral dimeric Mn(III) salen complexes using PhI(OAc)2 as an oxidant in the presence of various additives in water/organic solvent mixture. Excellent ee (up to 99%) of chiral secondary alcohols was achieved in 0.5 h. The catalyst 1A was recovered easily and reused five times with retention of enantioselectivity.
Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 274, Issues 1–2, 3 September 2007, Pages 120–126
Journal: Journal of Molecular Catalysis A: Chemical - Volume 274, Issues 1–2, 3 September 2007, Pages 120–126
نویسندگان
Kavita Pathak, Irshad Ahmad, Sayed H.R. Abdi, Rukhsana I. Kureshy, Noor-ul H. Khan, Raksh V. Jasra,