کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
67860 48496 2008 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electronic, steric, and temperature effects in the Pd(II)-biquinoline catalyzed aerobic oxidation of benzylic alcohols in water
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Electronic, steric, and temperature effects in the Pd(II)-biquinoline catalyzed aerobic oxidation of benzylic alcohols in water
چکیده انگلیسی

The Pd-catalyzed aerobic oxidation of various benzyl alcohol derivatives was investigated. Product selectivity is highly dependent on the nature and position of the substituents on the alcohol as well as the level of catalyst loading. Electron-donating substituents increase the reaction rate (ρ = −0.37), which suggests a partial reduction of the palladium center coupled with alcohol oxidation in the rate-limiting step. The temperature dependence of 4-methoxybenzyl alcohol oxidation was also evaluated, providing activation parameters of ΔH‡ = 7.4(4) kcal/mol and ΔS‡ = −53(1) eu. Water is used as the only reaction solvent and air is used as the sole oxidant throughout these studies.

The Pd-catalyzed aerobic oxidation of various benzyl alcohol derivatives was investigated. Product selectivity is highly dependent on the nature and position of the substituents on the alcohol as well as the level of catalyst loading. An examination of electronic effects reveals that electron-donating substituents increase the reaction rate. The temperature dependence of 4-methoxybenzyl alcohol oxidation was also evaluated.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 284, Issues 1–2, 2 April 2008, Pages 149–154
نویسندگان
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