کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
67936 | 48499 | 2007 | 5 صفحه PDF | دانلود رایگان |
Introducing bis(oxazole) ligands to catalysis: novel bis(oxazole) ligands could be readily synthesized from isophthaloyl dichlorides and ethyl glycinate hydrochlorides or 6-aminoacetophenone hydrochloride. Their corresponding pincer palladium complexes proved to be extremely robust catalysts for Suzuki-Miyaura cross coupling reactions, allowing the synthesis of biaryls under aerobic conditions with turn over numbers of up to 790,000 and turn over frequencies of up to 49,000 h−1.
Introducing bis(oxazole) pincer ligands to catalysis: the bis(oxazole) pincer palladium complex A proved to be an extremely robust catalyst for Suzuki-Miyaura cross coupling reactions, allowing the synthesis of biaryls under aerobic conditions with high turn over numbers and rates. Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 268, Issues 1–2, 1 May 2007, Pages 65–69