کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
68009 | 48500 | 2007 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Epoxidation catalyzed by iron(III) and manganese(III) pyridine-2-carboxamido complexes Epoxidation catalyzed by iron(III) and manganese(III) pyridine-2-carboxamido complexes](/preview/png/68009.png)
A series of Fe(III) and Mn(III) complexes containing N4 non-porphyrin pyridine-2-carboxamido ligands have been synthesized. Their catalytic abilities in epoxidation and the effects of reaction conditions such as temperature, solvent have been studied, leading to the highest yield of 92% for 4-methoxystyrene by using [Mn(bbpc)Cl(DMF)] (H2bbpc = 1,2-bis(4′-tert-butylpyridine-2′-carboxamido)-4,5-dichlorobenzene) as catalyst.
A series of Fe(III) and Mn(III) complexes containing tetradentate pyridine-2-carboxamido ligands have been synthesized and their applications in epoxidation have been studied with the best yield of 92% for 4-methoxylstyrene by using [Mn(bbpc)Cl(DMF)] (H2bbpc = 1,2-bis(4′-tert-butylpyridine-2′-carboxamido)-4,5-dichloro-benzene) as catalyst. Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 266, Issues 1–2, 2 April 2007, Pages 284–289