کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
68122 | 48503 | 2007 | 14 صفحه PDF | دانلود رایگان |

Neutral and bis-cationic palladium(II) complexes with 1,2-bis(di(2-methoxyphenyl)phosphino)ethane (o-MeO-dppe) and 1,3-bis(di(2-methoxyphenyl)phosphino)propane (o-MeO-dppp) have been synthesized and employed to catalyze the CO-ethylene copolymerization reaction in either protic or aprotic solvents. A comparison of the catalytic performance of these complexes with that of analogous precursors stabilized by 1,2-bis(diphenylphosphino)ethane (dppe) and 1,3-bis(diphenylphosphino)propane (dppp) ligands has shown significant differences in terms of catalytic productivity and molecular weight. In situ and operando high-pressure NMR experiments have provided valuable information on catalysis resting states and intermediates and have contributed to rationalize the observed productivity as well.
CO-ethene copolymerization reactions in different reaction media catalyzed by palladium(II) complexes with chelating diphosphines bearing ortho-methoxy-substituted aryl groups. Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 265, Issues 1–2, 16 March 2007, Pages 292–305