کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
68239 48508 2007 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Iron(II) coordination compounds with ω-alkenyl substituted bis(imino)pyridine ligands: Self-immobilizing catalysts for the polymerization of ethylene
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Iron(II) coordination compounds with ω-alkenyl substituted bis(imino)pyridine ligands: Self-immobilizing catalysts for the polymerization of ethylene
چکیده انگلیسی

Coordination compounds of iron(II)chloride with bis(imino)pyridine ligands bearing ω-alkenyl substituents were synthesized and characterized. They can be activated with methylalumoxane (MAO) and then be used as self-immobilizing catalysts for the polymerization of ethylene. The produced polyethylene has a monomodal molecular weight distribution which is in contrast to polyethylenes that are produced with the unsubstituted catalysts.

Coordination compounds of iron(II) chloride with bis(imino)pyridine ligands bearing ω-alkenyl substituents were synthesized and characterized. They can be activated with methylalumoxane (MAO) and then be used as self-immobilizing catalysts for the polymerization of ethylene. The produced polyethylene has a monomodal molecular weight distribution which is in contrast to polyethylenes that are produced with the unsubstituted catalysts. Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 261, Issue 2, 18 January 2007, Pages 246–253
نویسندگان
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