کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
68239 | 48508 | 2007 | 8 صفحه PDF | دانلود رایگان |

Coordination compounds of iron(II)chloride with bis(imino)pyridine ligands bearing ω-alkenyl substituents were synthesized and characterized. They can be activated with methylalumoxane (MAO) and then be used as self-immobilizing catalysts for the polymerization of ethylene. The produced polyethylene has a monomodal molecular weight distribution which is in contrast to polyethylenes that are produced with the unsubstituted catalysts.
Coordination compounds of iron(II) chloride with bis(imino)pyridine ligands bearing ω-alkenyl substituents were synthesized and characterized. They can be activated with methylalumoxane (MAO) and then be used as self-immobilizing catalysts for the polymerization of ethylene. The produced polyethylene has a monomodal molecular weight distribution which is in contrast to polyethylenes that are produced with the unsubstituted catalysts. Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 261, Issue 2, 18 January 2007, Pages 246–253