کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
683245 888998 2010 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The transesterification of rapeseed and waste sunflower oils: Mass-transfer and kinetics in a laboratory batch reactor and in an industrial-scale reactor/separator setup
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی تکنولوژی و شیمی فرآیندی
پیش نمایش صفحه اول مقاله
The transesterification of rapeseed and waste sunflower oils: Mass-transfer and kinetics in a laboratory batch reactor and in an industrial-scale reactor/separator setup
چکیده انگلیسی

We have investigated the transesterification of rapeseed (RO) and waste sunflower (SO) oils with methanol in the presence of potassium hydroxide as a catalyst. The transesterification of tri-acylglycerols was first conducted in a batch reactor. The effect of the temperature on the reaction rates was studied at a constant molar ratio of the alcohol to tri-acylglycerols (6:1) and for a constant concentration of the catalyst (1.0 wt%). Size-exclusion chromatography and 1H NMR spectroscopy were used to quantitatively monitor the transesterification reaction. The mass-transfer coefficients of the tri-acylglycerols during the initial transesterification stage were found to be 0.2–1.2 × 10−5 m min−1, depending on the type of oil and the temperature. Calculated activation energies implied that at higher temperatures the formation of mono-acylglycerols and glycerole was favored for the SO (93 kJ/mol for the forward and 48 kJ/mol for the backward reaction) and the RO (47 kJ/mol for the forward and 36 kJ/mol for the backward reaction), respectively. For the continuous industrial reactor/separator setup, the optimum methanol recycle ratio was established as 0.0550.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Bioresource Technology - Volume 101, Issue 10, May 2010, Pages 3333–3344
نویسندگان
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