کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
684059 | 889014 | 2010 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Rapid microwave-assisted transesterification of yellow horn oil to biodiesel using a heteropolyacid solid catalyst Rapid microwave-assisted transesterification of yellow horn oil to biodiesel using a heteropolyacid solid catalyst](/preview/png/684059.png)
An efficient microwave-assisted transesterification (MAT) technique was developed to prepare biodiesel from yellow horn (Xanthoceras sorbifolia Bunge.) oil with a heteropolyacid (HPA) catalyst namely Cs2.5H0.5PW12O40. A study for optimizing the reaction conditions such as reaction temperature, time, molar ratio of methanol/oil, catalyst amount, and recycle number of catalyst has been performed. The maximum yield of fatty acid methyl esters (FAMEs) reached 96.22% under optimal conditions of temperature 60 °C, 10 min, molar ratio of methanol/oil 12:1, 1% (w/w of oil) catalyst and minimum recycle number nine times. The final product of biodiesel, obtained after the new catalyzed process, was analyzed by gas chromatography. The results showed that the Cs2.5H0.5PW12O40 heterogeneous acid catalyst had higher efficiency for transesterification under microwave irradiation compared with the conventional method. The product properties of yellow horn biodiesel are found to be in agreement with EN 14214 standard.
Journal: Bioresource Technology - Volume 101, Issue 3, February 2010, Pages 931–936