کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
68469 48515 2006 16 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Design and study of homogeneous catalysts for the selective, low temperature oxidation of hydrocarbons
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Design and study of homogeneous catalysts for the selective, low temperature oxidation of hydrocarbons
چکیده انگلیسی

The direct, low temperature conversion of hydrocarbons to functionalized products using novel, single site catalysts could lead to technological advances that redefine the landscape of the current materials and energy industries. Natural gas continues to represent a vast source of untapped hydrocarbons around the globe that has the potential to replace or augment petroleum as the raw material for materials and energy. Its abundance has garnered much interest in the scientific community as groups have focused on the catalytic conversion of its major component, methane, to functionalized products. The key requirements is to design new catalysts for the oxidative functionalization of methane that operate at lower temperatures and that also meet the basic requirements of selectivity, rate, and lifetime that characterize useful catalysts. Recent advances in the field of hydrocarbon CH activation have shown the potential for transition metal based coordination catalysts to meet these requirements. Described herein are recent advances in designing catalysts based on the CH activation reaction that address the basic requirements for practical systems with emphasis on the issues that have prevented promising reported systems from becoming commercially viable.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 251, Issues 1–2, 17 May 2006, Pages 8–23
نویسندگان
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