کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
68657 | 48519 | 2006 | 8 صفحه PDF | دانلود رایگان |

An asymmetric high-pressure (ca. 10 kbar) reaction of various 2-alkylfurans and atmospheric-pressure reaction of 2-methoxyfuran with alkyl glyoxylates, catalyzed by the chiral (salen)Co complexes, has been studied. The reaction afforded chiral furfuryl alcohols, compounds of significant synthetic interest, with moderate to good enantioselectivity (up to 76% ee).
An asymmetric high-pressure (ca. 10 kbar) reaction of various 2-alkylfurans and atmospheric-pressure reaction of 2-methoxyfuran with alkyl glyoxylates, catalyzed by the chiral (salen)Co complexes, has been studied. The reaction afforded chiral furfuryl alcohols, compounds of significant synthetic interest, with moderate to good enantioselectivity (up to 76% ee). Figure optionsDownload as PowerPoint slide
Journal: Journal of Molecular Catalysis A: Chemical - Volume 257, Issues 1–2, 1 September 2006, Pages 124–131