کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
69067 48529 2006 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Reduction of ketones and aldehydes to alcohols with magnesium–aluminium mixed oxide and 2-propanol
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Reduction of ketones and aldehydes to alcohols with magnesium–aluminium mixed oxide and 2-propanol
چکیده انگلیسی

The Meerwein–Ponndorf–Verley (MPV) reaction allowed the successful reduction of various aldehydes and ketones by using an MgAlOx mixed oxide previously obtained from a layered double hydroxide as catalyst and 2-propanol as hydrogen donor. The reaction exhibited good yield and selectivity towards the corresponding alcohol in all cases. The results were quite consistent with a mechanism involving adsorption of the reactants on an acid–base pair in the catalyst.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 246, Issues 1–2, 1 March 2006, Pages 190–194
نویسندگان
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